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Developments in electrochemistry : science inspired by Martin Fleischmann / editors, Derek Pletcher, Zhong-Qun Tian, David E. Williams. -- Chichester, West Sussex : John Wiley & Sons, Inc., 2014. – (54.24/D489) |
Contents
Contents
1 Martin Fleischmann - The Scientist and the Person
2 A Critical Review of the Methods Available for Quantitative Evaluation of Electrode Kinetics at Stationary Macrodisk Electrodes
2.1 DC Cyclic Voltammetry
2.2 AC Voltammetry
2.3 Experimental Studies
2.4 Conclusions and Outlook
References
3 Electrocrystallization: Modeling and Its Application
3.1 Modeling Electrocrystallization Processes
3.2 Applications of Models
3.3 Summary and Conclusions
References
4 Nucleation and Growth of New Phases on Electrode Surfaces
4.1 An Overview of Martin Fleischmann's Contributions to Electrochemical
4.2 Electrochemical Nucleation with Diffusion-Controlled Growth
4.3 Mathematical Modeling of Nucleation and Growth Processes
4.4 The Nature of Active Sites
4.5 Induction Times and the Onset of Electrochemical Phase Formation Processes
4.6 Conclusion
References
5 Organic Electrosynthesis
5.1 Indirect Electrolysis
5.2 Intermediates for Families of Reactions
5.3 Selective Fluorination
5.4 Two-Phase Electrolysis
5.5 Electrode Materials
5.6 Towards Pharmaceutical Products
5.7 Future Prospects
References
6 Electrochemical Engineering and Cell Design
6.1 Principles of Electrochemical Reactor Design
6.2 Decisions During the Process of Cell Design
6.3 The Influence of Electrochemical Engineering on the Chlor-Alkali Industry
6.4 Parallel Plate Cells
6.5 Redox Flow Batteries
6.6 Rotating Cylinder Electrode Cells
6.7 Conclusions
References
7 Electrochemical Surface-Enhanced Raman Spectroscopy (EC-SERS): Early History， Principles， Methods， and Experiments 113
7.1 Early History of Electrochemical Surface-Enhanced Raman Spectroscopy
7.2 Principles and Methods of SERS
7.3 Features of EC-SERS
7.4 EC-SERS Experiments
Acknowledgments
References
8 Applications of Electrochemical Surface-Enhanced Raman Spectroscopy (EC-SERS)
8.1 Pyridine Adsorption on Different Metal Surfaces
8.2 Interfacial Water on Different Metals
8.3 Coadsorption of Thiourea with Inorganic Anions
8.4 Electroplating Additives
8.5 Inhibition of Copper Corrosion
8.6 Extension of SERS to the Corrosion of Fe and Its Alloys: Passivity
8.7 SERS of Corrosion Inhibitors on Bare Transition Metal Electrodes
8.8 Lithium Batteries
8.9 Intermediates of Electrocatalysis
Acknowledgments
References
9 In-Situ Scanning Probe Microscopies: Imaging and Beyond
9. l Principle of In-Situ STM and In-Situ AFM
9.2 In-Situ STM Characterization of Surface Electrochemical Processes
9.3 In-Situ AFM Probing of Electric Double Layer
9.4 Electrochemical STM Break-Junction for Surface Nanostructuring and Nanoelectronics and Molecular Electronics
9.5 Outlook
References
10 In-Situ Infrared Spectroelectrochemical Studies of the Hydrogen Evolution Reaction 183
10.1 The H+/H2 Couple
10.2 Single-Crystal Surfaces
10.3 Subtractively Normalized Interfacial Fourier Transform Infrared Spectroscopy
10.4 Surface-Enhanced Raman Spectroscopy
10.5 Surface-Enhanced IR Absorption Spectroscopy
10.6 In-Situ Sum Frequency Generation Spectroscopy
10.7 Spectroscopy at Single-Crystal Surfaces
10.8 Overall Conclusions
References
11 Electrochemical Noise: A Powerful General Tool
11.1 Instrumentation
11.2 Applications
11.3 Conclusions
References
12 From Microelectrodes to Scanning Electrochemical Microscopy
12.1 The Contribution of Microelectrodes to Electroanalytical Chemistry
12.2 Scanning Electrochemical Microscopy (SECM)
12.3 Conclusions
References
13 Cold Fusion After A Quarter-Century: The Pd/D System
13.1 The Reproducibility Issue
13.2 Palladium-Deuterium Loading
13.3 Electrochemical Calorimetry
13.4 Isoperibolic Calorimetric Equations and Modeling
13.5 Calorimetric Approximations
13.6 Numerical Integration of Calorimetric Data
13.7 Examples of Fleischmann's Calorimetric Applications
13.8 Reported Reaction Products for the Pd/D System
13.9 Present Status of Cold Fusion
Acknowledgments
References
14 In-Situ X-Ray Diffraction of Electrode Surface Structure 261
14.1 Early Work
14.2 Synchrotron-Based In-Situ XRD
14.3 Studies Inspired by Martin Fleischmann's Work
14.4 Conclusions
References
15 Tribocorrosion
15.1 Introduction and Definitions
15.2 Particle-Surface Interactions
15.3 Depassivation and Repassivation Kinetics
15.4 Models and Mapping
15.5 Electrochemical Monitoring of Erosion-Corrosion
15.6 Tribocorrosion within the Body: Metal-on-Metal Hip Joints
15.7 Conclusions
Acknowledgments
References
16 Hard Science at Soft Interfaces
16.1 Charge Transfer Reactions at Soft Interfaces
16.2 Electrocatalysis at Soft Interfaces
16.3 Micro- and Nano-Soft Interfaces
16.4 Plasmonics at Soft Interfaces
16.5 Conclusions and Future Developments
References
17 Electrochemistry in Unusual Fluids
17.1 Electrochemistry in Plasmas
17.2 Electrochemistry in Supercritical Fluids
17.3 Conclusions
Acknowledgments
References
18 Aspects of Light-Driven Water Splitting
18.1 A Very Brief History of Semiconductor Electrochemistry
18.2 Thermodynamic and Kinetic Criteria for Light-Driven Water Splitting
18.3 Kinetics of Minority Carrier Reactions at Semiconductor Electrodes
18.4 The Importance of Electron-Hole Recombination
18.5 Fermi Level Splitting in the Semiconductor-Electrolyte Junction
18.6 A Simple Model for Light-Driven Water-Splitting Reaction
18.7 Evidence for Slow Electron Transfer During Light-Driven Water Splitting
18.8 Conclusions
Acknowledgments
References
19 Electrochemical Impedance Spectroscopy
19.1 Theory
19.2 The Point Defect Model
19.3 The Passivation of Copper in Sulfide-Containing Brine
19.4 Summary and Conclusions
Acknowledgments
References
Index
