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Synthetic Macromolecules with higher structural order / Ishrat M. Khan, editor. — Washington, DC : American Chemical Society, c2002.—(54.57083/S993)

Contents

    Contents
    
    Preface ix
    1. Synthetic Macromolecules with Higher Structural Order: An Overview 1
     Ishrat M. Khan
    Higher Ordering in Synthetic Polymers
    2. Synthesis of Single-Handed Helical Polymethacrylates from Designed Bulky Monomers by Anionic and Free Radical Catalyses 11
     Yoshio Okamoto, Kumiko Tsunematsu, Kiyoko Ueda, Yasuaki Hidaka, Naotaka Kinjo, and Tamaki Nakano
    3. Profile of the Helical Structure of Poly(propiolic esters) 25
     Ryoji Nomura, Hideo Nakako, Yasunori Fukushima, and Toshio Masuda
    4. Helicity Induction on Optically Inactive Polyacetylenes and Polyphosphazenes 41
     Eiji Yashima and Katsuhiro Maeda
    5. Helical and Higher Structural Ordering in Poly(3-methyl-4-vinylpyridine) 55
     Lisandra J. Ortiz, Lawrence Pratt, Kimberly Smitherman, Biswajit Sannigrahi, and Ishrat M. Khan
    6. Helical Poly(diarylsilylenes): Effects of Higher Order Structure on Optical Activity 67
     Julian R. Koe, Michiya Fujiki, Hiroshi Nakashima, and Masao Motonaga
    7. Structured Polymers with Stimuli-Responsive Chiroptical Behavior: Azobenzene-Modified Helical Constructs 87
     Gary D. Jaycox
    Synthetic Peptides
    8. Collagen Mimics: Synthesis and Properties of Disulfide-Bridged Trimeric Collagen Peptides 103
     Luis Moroder, Stella Fiori, Rainer Friedrich, J. Constanze D. Mtiller, and Johannes Ottl
    9. Peptide-Amphiphile Induction of a-Helical and Triple-Helical Structures 117
     Gregg B. Fields, Pilar Forns, Katarzyna Pisarewicz, and Janelle L. Lauer-Fields
    Macromolecular Assemblies
    10. Synthesis, Helical Chirality, and Self-Assembling Hierarchical Structures of Amino Acid-Containing Polyacetylenes 133
     Ben Zhong Tang, Kevin K. L. Cheuk, Fouad Salhi, Bingshi Li, Jacky W. Y. Lain, John A. K. Cha, and Xudong Xiao
    11. Self-Assembly of Ferrocene-Based Block Copolymers: A Route to Supramolecular Organometailic Materials 149
     K. Nicole Power-Billard, Jason Massey, Rui Resendes, Mitchell A. Winnik, and Ian Manners
    12. Toward Functional Architectures via Terpyridine-Based Metallo-Supramolecular Initiators 163
     U. S. Schubert, G. Hochwimmer, and M. Heller
    13. Reversed-Type Micelle Formation Property of End-Glycosidated Polystyrene 177
     Toyoji Kakuchi and Naoya Sugimoto
    14. Ultracentrifugation Studies on the Solution Properties of Supramolecular Building Blocks for Polymers: Potential, Problems, and Solutions 185
     C. Tziatzios, H. Durchschlag, C. H. Weidl, C. Eschbaumer, W. Maechtle, P. Schuck, U. S. Schubert, and D. Schubert
    15. Dendritic Methodology Applied to the Prediction, Design, and Synthesis of Sol-Gel Materials 201
     Theodore F. Baumann, Glenn A. Fox, and Andrew L. Vance
    Author Index 215
    Subject Index 217