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Molecular recognition and polymers : control of polymer structure and self-assembly / edited by Vincent M. Rotello, S. Thayumanavan. — Hoboken, N.J. : Wiley, c2008. – (54.573/M718) |
Contents
CONTENTS
Preface
Acknowledgments
List of Contributors
List of Figures
List of Tables
Editor Biographies
PART I FUNDAMENTALS OF SUPRAMOLECULAR POLYMERS
1. A BRIEF INTRODUCTION TO SUPRAMOLECULAR CHEMISTRY IN A POLYMER CONTEXT
1.1. Introduction and Background / 3
1.2. Main-Chain Versus Side-Chain Supramolecular Polymers / 4
References / 6
2. MOLECULAR RECOGNITION USING AMPHIPHILIC MACROMOLECU LES
2.1. Introduction / 9
2.2. Amphiphilic Block Copotymers / 11
2.3. Amphiphilic Homopolymers / 22
2.4. Amphiphilic Dendrimers / 29
2.5. Conclusions / 29
Acknowledgment / 30
References / 30
3. SUPRAMOLECULAR CONTROL OF MECHANICAL PROPERTIES IN SINGLE MOLECULES， INTERFACES， AND MACROSCOPIC MATERIALS
3.1. Introduction and Background / 37
3.2. Mechanical Properties of Linear SPs / 40
3.3. Mechanical Properties of SP Networks / 46
3.4. Mechanical Properties in SPs at Interfaces / 50
3.5. Mechanical Forces and Supramolecular Interactions / 55
3.6. Conclusions / 57
References / 58
PART II POLYMER FORMATION AND SELF-ASSEMBLY 63
4. HYDROGEN BOND FUNCTIONALIZED BLOCK COPOLYMERS AND TELECHELIC OLIGOMERS
4.1. Scientific rationale and perspective
4.2. Hydrogen bonding interactions in macromolecular design
4.3. Hydrogen Bond Containing Block Copolymers / 73
4.4. Telechelic Hydrogen Bond Functional Polymers / 85
4.5. Combining Hydrogen Bonding with Other Noncovalent Interactions / 90
4.6. Reversible Attachment of Guest Molecules via Hydrogen Bonding / 91
4.7. Conclusions and Summary / 93
References / 94
5. NONCOVALENT SIDE CHAIN MODIFICATION 103
5.1. Introduction / 103
5.2. Strategies Toward Noncovalent Side Chain Functionalization of Polymeric Scaffolds / 105
5.3. Noncovalent Multifunctionalization of the Side Chains of Polymeric Scaffolds / 111
5.4. Applications of Noncovalently Functionalized Side Chain Copolymers / 118
5.5. Conclusions and Outlook / 131
Acknowledgments / 132
References / 132
6. POLYMER-MEDIATED ASSEMBLY OF NANOPARTICLES USING ENGINEERED INTERACTIONS
6.1. Introduction / 137
6.2. Design of Nanoparticles and Polymers / 138
6.3. Self-Assembly of Polymer-Particle Nanocomposites / 139
6.4. Conclusions and Outlook / 151
References / 151
7. METALLOSUPRAMOLECULAR POLYMERS， NETWORKS， AND GELS
7.1. Introduction / 157
7.2. Metal-Ligand Binding Motifs / 159
7.3. Linear and Macrocyclic Main Chain MSPs / 161
7.4. Metallosupramolecular Networks and Gels / 169
7.5. Conclusion and Outlook / 175
References / 175
8. POLYMERIC CAPSULES: CATALYSIS AND RUG DELIVERY
8.1. Introduction / 179
8.2. Methods of Encapsulation / 180
8.3. Catalyst Encapsulation / 186
8.4. Drug Delivery with Microcapsules / 191
8.5. Conclusion / 197
References / 197
9. SEQUENCE-SPECIFIC HYDROGEN BONDED UNITS FOR DIRECTED ASSOCIATION， ASSEMBLY， AND LIGATION
9.1. Introduction / 207
9.2. General Design: Information-Storing Molecular Duplexes Based on the Recombination of H Bond Donors and Acceptors / 208
9.3. Quadruply H Bonded Duplexes with Sequence-Independent Stability / 209
9.4. Tuning Binding Strength by Varying the Number of Interstrand H Bonds / 212
9.5. Probing Sequence Specificity / 213
9.6. Unexpected Discovery: Duplexes Containing Folded Strands / 216
9.7. Directed Assembly: Formation of/3-Sheets and Supramolecular Block Copolymers / 219
9.8. Integrating Noncovalent and Covalent Interactions: Directed Olefin Metathesis and Disulfide Bond Formation / 223
9.9. Conclusions and Future Perspectives / 230
Acknowledgments / 231
References / 231
10. BIOINSPIRED SUPRAMOLECULAR DESIGN IN POLYMERS FOR ADVANCED MECHANICAL PROPERTIES
10.1. Introduction / 235
10.2. Biomimetic Concept of Modular Polymer Design / 237
10.3. Results and Discussion / 240
10.4. Conclusion and Perspective / 251
Acknowledgments / 253
References / 253
11. STRUCTURE AND SELF-ASSEMBLY OF AMPHIPHILIC DENDRIMERS IN WATER
11.1. Introduction / 259
11.2. Structure / 260
11.3. Self-Assembly and Aggregation / 269
11.4. Folded Amphiphilic Dendrimers / 283
11.5. Langmuir-Blodgett Monolayers / 289
11.6. Conclusion / 297
References / 297
PART III BIOMOLECULAR RECOGNITION USING POLYMERS
12. COLORIMETRIC SENSING AND BIOSENSING USING FUNCTIONALIZED CONJUGATED POLYMERS
12.1. Introduction / 309
12.2. PDA / 310
12.3. Polythiophenes / 323
12.4. Other Materials / 328
12.5. Conclusion / 328
References / 329
13. GLYCODENDRIMERS AND OTHER MACROMOLECULES BEARING MULTIPLE CARBOHYDRATES
13.1. Introduction / 335
13.2. Dendrimers to Glycodendrimers / 338
13.3. Multivalency / 342
13.4. Heteromultivalent Carbohydrate Systems / 345
13.5. Comments Regarding the Synthesis of Heteromultivalent Carbohydrate Systems / 347
13.6. Electron Paramagnetic Resonance (EPR) Characterization of Heterogeneously Functionalized Dendrimers / 348
13.7. Conclusions and Outlook / 353
Acknowledgment / 354
References / 354
14. SUPRAMOLECULAR POLYMERIZATION OF PEPTIDES AND PEPTIDE DERIVATIVES: NANOFIBROUS MATERIALS
14.1. Introduction / 359
14.2. Self-Assembly of Nanofibers Based on a-Helices / 361
14.3. Nanofibers Self-Assembled from fl-Sheets / 369
14.4. Collagen Mimetics / 383
14.5. Conclusions / 387
References / 387
15. MOLECULAR IMPRINTING FOR SENSOR APPLICATIONS
15.1. Introduction to Sensing Platforms / 395
15.2. Synthesis of MIPs / 397
15.3. Recognition Properties of MIPs / 405
15.4. Polymer Formats and Morphologies / 409
15.5. Application of MIPs in Sensing / 413
15.6. Conclusions and Outlook / 420
References / 420
Index
